The tubes are coated inside and out and as I mentioned, there is a notable reduction in heat radiating from the headers that are coated vs un-coated. I have no financial interest or benefit in making supporting claims to coatings but they do make a difference.
Check out this video for a professional review: skip to 5:00
Header test
Yeah, so the guys in the video make the same mistake trying to use an infrared thermometer to measure temperature of an object that's been coated with an infrared blocker. So any conclusions they might draw from those erroneous measurements aren't worth the electrons it took to record them. And I had a good laugh when they said they could "feel the heat". No, they can't, unless they actually touch it, which I don't recommend at all.
What they can feel from a distance is the heating effect of their skin absorbing infrared, similar to their no-touch "thermometers". Heat doesn't radiate, infrared light does. The difference may seem irrelevant, unless it leads you to believe something dangerous isn't. As an engineer, I have to know the difference, and I notice stuff like that (you're welcome).
So as I said, it may be useful in and of itself to block infrared. How much of the heat transferred from hot exhaust gas to manifold (or header) is due to contact vs. how much due to the incandescence of the gas (and re-absorption of radiation by manifold)?
I don't know the answer to that, but suspect the majority is by contact. It would be interesting to test that. In either case, the coating may at least reduce under-hood temperatures by reducing transmission and re-absorption by fenders and other parts.
As to the headers themselves, my gut says if you make an accurate contact measurement of the coated header surface (with a thermocouple for example), you'll find it to be basically as hot as an uncoated header under the same conditions.
I draw no negative conclusions about the coating product, and if I ever decide to install headers may consider using it myself. Just seeking clearer understanding of what it does and doesn't do.