2020 RAM DT 3.0L Ecodiesel with 33 Gallon tank has a 5.5 gallon DEF tank.
I haven't seen it posted and the manual did not offer up the information, this seems a good place to mention it. I found this by letting the DEF gauge get to ~empty, indicated by it telling me it would not restart in 50 miles and the needle riding the empty line. I added 2x 2.5 gallon Blue DEF boxes, and used a single gallon container and deep funnel to add little sips until I could see the top of the fluid with a flashlight down the funnel. She took just under .4 gallons from the bottle, based roughly on the little measuring lines on the side, which suggests to me the tank is 5.5 Gallons. Now that I've risked the dangers of urea spillage and filled her more than is probably wise, you won't have to.