Gotta go off the tire inflation tables. Find the similar weight carrying spec for your OEM size, and then find that same weight carrying capacity for your new tire SIZE and LOAD RANGE.
That's the theory anyway.
Then, I usually go down a bit because the OEM PSI is meant for at capacity hauling, and I also ensure my rear PSI is 10% or so less than front when the bed is empty.
That's what I've done for about a decade now, because these E range tires on a half ton are so dang stiff that the chalk test for me has proven useless. I get the same results between 25-50 PSI.